Dielectric spectroscopy of natural rubber-cellulose II nanocomposites

Cellulose nanocrystal reinforced oxidized natural rubber nanocomposites.

Natural rubber (NR) latex particles were oxidized using KMnO4 as oxidant to promote the insertion of hydroxyl groups in the surface polyisoprene chains. Different degrees of oxidation were investigated. Both unoxidized and oxidized NR (ONR) latex were used to prepare nanocomposite films reinforced with cellulose nanocrystals (CNCs) by casting/evaporation. The oxidation of NR was carried out to ...

Cellulose Based Rubber Nanocomposites

This chapter gives an introduction on the general aspects of cellulose, natural rubber and their bionanocomposites. A brief literature review on what has been done so far on the cellulose, natural rubber nanocomposites research area is also included in this chapter. This chapter also describes the structure, properties and characterization of cellulose as a biobased nanomaterial in natural rubber.

Natural rubber-clay nanocomposites

The mechanical properties of non-vulcanized natural rubber and dialyzed natural rubber-clay nanocomposites have been studied by uniaxial deformations to evaluate the reinforcement efficiency of the clay. We show that while non-rubber molecules contribute to auto-reinforcement, removal of these molecules improves significantly the performance of clay as reinforcement agent. These mechanical prop...

Rubber Clay Nanocomposites

The Cyclization of Natural Rubber

The effects of solvent, temperature, time, weight percent of catalyst on the rate and mechanism of cyclization of natural rubber (NR) was studied in toluene and xylene solutions having tin tetra chloride catalyst (SnCl4). Iodometric titration show, with 8% SnCl4 (based on polymer weight) cyclization occurs, leaving 27.4% of the total unsaturation. Infrared spectra of c...